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While Aang defeated Ozai, Zuko, with the help of Katara, defeated his younger sister, Princess Azula, and took his place as Fire Lord, declaring the end of the Hundred Year War and the start of a new era of love and peace. He instead joined the Avatar's group to become Aang's lifelong friend and firebending mentor and was determined to end the war and restore both his and the Fire Nation's honor. With support from his paternal uncle, General Iroh, and after much internal struggle and turmoil, Zuko rejected Ozai and his model of the Fire Nation. He is recognizable by the distinctive burn scar on the left side of his face from his eyebrow to his cheek, which was given to him by his father, Fire Lord Ozai, shortly before his banishment as a result of an incident in which he unintentionally disrespected his father by speaking out of turn and refusing to duel him. Originally the primary enemy of Team Avatar, Zuko devoted three years to trying to capture the long-lost Avatar to end his banishment and regain his honor as Crown Prince of the Fire Nation. More about Zuko History Book Two: Earth (Spring 100 AG) Book Three: Fire (Summer 100 AG) Post war (Summer 100 AG - 102 AG) Relationships Zuko's relationships Other Media Zuko in the films Zuko in the games Zuko in The Last Airbender video game Zuko in the pilot episode Image gallery (384) Zuko is a firebending master, born as a prince in the Fire Nation Royal Family, who reigned as Fire Lord from 100 AG until his abdication in 167 AG.